A universal mechanism of the planar boron rotors B11-, B13+, B15+ and B19- inner wheels rotating in pseudo-rotating outer bearings    

   Planar boron clusters B₁₁⁻, B₁₃⁺, B₁₅⁺, and B₁₉⁻ have been intro-duced recently as molecular Wankel motors or tank treads. Here we present a universal mechanism for these dynamically fluxional clusters; that is, they are molecular rotors with inner wheels that rotate almost freely in pseudo-rotating outer bearings, analogous to rotating molecules trapped in pseudo-rotating cages. This mechanism has significant quantum mechanical consequences: the global-minimum structures of the clusters have C_2v symmetry, whereas the wheels rotating in pseudo-rotating bearings generate rosette-type shapes with D_9h , D_10h , D_11h, and D_13h symmetries. The related rotational/pseudo-rotational energies appear with charac-teristic band structures, effecting the dynamics.